{"created":"2023-07-25T10:24:30.443425+00:00","id":1828,"links":{},"metadata":{"_buckets":{"deposit":"78620f1c-3216-426c-84c5-681b9a5c21f5"},"_deposit":{"created_by":1,"id":"1828","owners":[1],"pid":{"revision_id":0,"type":"depid","value":"1828"},"status":"published"},"_oai":{"id":"oai:hiroshima-cu.repo.nii.ac.jp:00001828","sets":["1:215"]},"author_link":["7583","7582","7580","7581"],"item_10001_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2016-09-28","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"12","bibliographicPageEnd":"124304-13","bibliographicPageStart":"124304-1","bibliographicVolumeNumber":"145","bibliographic_titles":[{"bibliographic_title":"The Journal of Chemical Physics"}]}]},"item_10001_description_19":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_10001_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We have generated SiCN in a supersonic free expansion, and measured the laser induced fluorescence (LIF) spectrum. Prior to the experiments, ab initio calculations were carried out to obtain the information necessary for searching for the LIF signals. In addition to the ˜X 2Π state, the optimized structures of three excited states, 2Δ, 2Σ+, and 2Σ−, have been obtained. Guided by the predictions, the LIF excitation spectrum of SiCN was observed in the UV region. The rotational structure of the 000 band with the origin, 29 261.639 cm−1, indicated that the electronic transition is ˜A 2Δ–˜X 2Π. The spin-orbit (SO) constants of the ˜X 2Π and ˜A 2Δ states were determined to be 140.824 and 4.944 cm−1, respectively. In the ˜A 2Δ state, the Fermi resonance between the (0,20,0) 2Δ and (0,00,1) 2Δ vibronic levels was identified. The molecular constants of the ˜X 2Π state were determined through the simultaneous analysis of the combination differences derived from the present LIF data with the previously reported rotational transitions. The spectroscopic parameters of the ˜A 2Δ state were also obtained from the analysis where the constants of the ˜X 2Π state, derived above, were fixed at those values.","subitem_description_type":"Abstract"}]},"item_10001_description_6":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"This research was supported in part by the Ministry of Education, Science, Sports and Culture, Grant-in-Aid for Scientific Research C, No. 16510078, 2004, and by Hiroshima City University Grant for Special Academic Research (General Studies), No. 4105.","subitem_description_type":"Other"}]},"item_10001_publisher_8":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Institute of Physics"}]},"item_10001_relation_14":{"attribute_name":"DOI","attribute_value_mlt":[{"subitem_relation_type":"isIdenticalTo","subitem_relation_type_id":{"subitem_relation_type_id_text":"info:doi/10.1063/1.4962504","subitem_relation_type_select":"DOI"}}]},"item_10001_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_text":"http://dx.doi.org/10.1063/1.4962504"}],"subitem_relation_type_id":{"subitem_relation_type_id_text":"http://dx.doi.org/10.1063/1.4962504","subitem_relation_type_select":"DOI"}}]},"item_10001_rights_15":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"Copyright 2016 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics.The following article appeared in J. Chem. Phys. 145, 124304 (2016) and may be found at http://dx.doi.org/10.1063/1.4962504"}]},"item_10001_source_id_11":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00694991","subitem_source_identifier_type":"NCID"}]},"item_10001_source_id_9":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0021-9606","subitem_source_identifier_type":"ISSN"}]},"item_10001_version_type_20":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"FUKUSHIMA, Masaru"},{"creatorName":"フクシマ, マサル","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"7580","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"ISHIWATA, Takashi"},{"creatorName":"イシワタ, タカシ","creatorNameLang":"ja-Kana"}],"nameIdentifiers":[{"nameIdentifier":"7581","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"福島, 勝","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"7582","nameIdentifierScheme":"WEKO"}]},{"creatorNames":[{"creatorName":"石渡, 孝","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"7583","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2023-03-07"}],"displaytype":"detail","filename":"JCP145_124304.pdf","filesize":[{"value":"841.3 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"JCP145_124304.pdf","url":"https://hiroshima-cu.repo.nii.ac.jp/record/1828/files/JCP145_124304.pdf"},"version_id":"e2ef5c3d-ae98-444f-ad6c-a0208e76a44d"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Electronic spectrum of jet cooled SiCN","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Electronic spectrum of jet cooled SiCN"}]},"item_type_id":"10001","owner":"1","path":["215"],"pubdate":{"attribute_name":"公開日","attribute_value":"2023-03-07"},"publish_date":"2023-03-07","publish_status":"0","recid":"1828","relation_version_is_last":true,"title":["Electronic spectrum of jet cooled SiCN"],"weko_creator_id":"1","weko_shared_id":-1},"updated":"2023-07-25T10:42:27.836087+00:00"}